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In the title compound, [Cu(C 2 HCl 2 O 2 )(C 10 H 8 N 2 ) 2 ](C 2 HCl 2 O 2 )·2H 2 O, the Cu II  ion is bonded to two  N , N ′-bidentate 2,2′-bipyridyl ligands and one  O -monodentate 2,2-dichloro­acetate anion in a distorted CuON 4  trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O—H⋯O and O—H⋯Cl hydrogen bonds.

Bis(2,2′-bipyridyl)(dichloroacetato)copper(II) dichloroacetate dihydrate