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Inorganic-organic frameworks have been the subject of great interest for several decades, including much recent research into metalorganic frameworks, coordination polymers and other similar materials. Composed of inorganic moieties connected by organic linkers, they form 1-, 2and 3-D architectures with intriguing properties that arise from the combination of their constituent parts.[1] Perhaps the most diverse group of inorganic-organic frameworks is based on the tartaric acid ligand, (C4H6O6), due to its conformational and binding flexibility. Individual tartrate structures exhibit many different architectures and physical properties, such as chirality, porosity, magnetism, luminescence and dielectricity. Indeed, the first known ferroelectric material, Rochelle’s Salt, whose crystal structure was first determined in 1940, is a potassium sodium tartrate framework: KNa(C4H4O6)·4H2O. [2]

Phase behaviour of lithium tartrate framework isomers: kinetic and thermodynamic effects