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Interest in superprotonic crystals of MmHn(XO4) (m+n)/2 (М = K, Rb, Cs, NH4; X = S, Se, P) is associated with the solution to fundamental problems of modern condensed matter physics: establishment of structural conditionality of anomalies of physical properties with the aim of designing new functional materials. Superprotonic crystals belong to a special class. As opposed to other hydrogen-containing compounds, phase transitions in these crystals are accompanied by a hydrogen-bond network rearrangement, resulting in a radical change in the physicochemical properties; in particular, these transitions give rise to proton conductivity of about 10 –3 –10 –

Solid acid proton conductors: the influence of hydrogen subsystems on physical properties