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C283 resulting precipitates were characterized by Infrared Spectroscopy, X-ray diffraction and the morphology of crystals was observed by an optical microscope and a scanning electron microscope. The results showed that SOM influences not only on the agglomeration, morphology, size and polymorphism of the CaCO3 crystals but also narrows the range of calcium and carbonate critical concentrations necessary to induce nucleation, the “Crystals-Growing Space”. Thus, it appears evident that in gelling environment the SOM is able to select a specific calcium and carbonate concentration. That, respecting the supersaturation laws, confines the nucleation and growth processes.

Self-assembled crystalline materials of calcium carbonate and silica