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C489 to compare these structures with a range of similar structural motifs present in the literature. Conformational differences between our investigated dyes and those complexes with a different counter ion were revealed. This analysis motivated a general enquiry into the influence of the position of attached ligands on the pyridine unit within all known Ruthenium or Iron based dyes containing three bipyridyl groups. The extent of delocalisation of electron density in these pyridine groups was calculated via a bond length variation analysis [2]. This revealed that our complexes were much less delocalised (~4%) than N719 (up to 37%). This delocalisation of the pyridine ring is attributed to the superior charge transfer properties of N719 and thus its better performance in DSC operation. This work has contributed to the basic foundation of molecular engineering wherein lies the ultimate goal of being able to tailor dyes to meet a specific component design of a DSC device.

Crystal structure, local atomic order and metastable phases of zirconia-based nanoceramics for solid-oxide fuel cells