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P21 with Z = 2. The molecules are stacking along the b axis(Figs.) to construct two types of water channel structures (I and II) in the dihydrate crystal. The hydrogen bond donor/accepter distances suggest that the channel I forms stronger hydrogen bonds than channel II. Therefore, the first dehydration from dihydrate may occur through the channel II to form the monohydrate crystal without major m olecu la r c o n f o r m a t i o n change. Then the water in channel I may be eliminated w i th ro t a t i on o f t h e p h e n y l e t h y l s u b s t i t u e n t o f Lisinopril molecule.

What do polymorphs teach us about crystal nucleation and growth?