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1 in the Brand NO2derivatives of 1-phenylethanones (1,2). However, when the N atom in these structures is pyramidal, no distant dimers are formed and the N-H...C(aryl) contacts become evident. References: 1.Saraogi, I., Mruthyunjayaswamy, B. H. M., Ijare, O. B., Jadegoud, Y. & Guru Row, T. N. (2003). Acta Cryst. E59, o443-o444 2.Abdulla, R. F., Boyd, D. B., Jones, N. D. & Swartzendruber, J. K. (1985). J. Org. Chem. 50, 3502-3505.

The interaction between H-bond and polyhedral network in the polymorphs of aluminium hydroxide