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The crystal structure of 6-[4-(trans-4-pentylcyclohexyl)phenoxy] hexane-1,2-diol (hereafter, CP2OH) has been determined by X-ray diffraction techniques. The CP2OH molecule crystallizes in the monoclinic crystal system with space group C2/c (#15). The asymmetric unit consists of one crystallographically independent molecule of CP2OH, and the unit cell contains eight molecules of CP2OH. The CP2OH molecules crystallize in sheets of layered arrangement along [010] direction. The unit distance of 30 Å exists between neighbouring layers along the [010] direction. In each sheet of the layered structure of CP2OH, the molecules are aligned in an inclined manner in which the terminal hydroxyl groups lie in a headto-head fashion generated by hydrogen bonding interactions. The driving force behind the generation and stabilization of each sheet of the layered structure is attributed to the hydrogen bonded network between the terminal hydroxyl groups in the self assembled driven interactions amongst the CP2OH molecules. The intermolecular interactions are generally driven by hydrogen bonding and are also orientation dependent.

Intermolecular interaction-directed conformations of bridged bis(1,4-piperazine-2,5-diones)