
2,4‐Dinitrophenylhydrazine, redetermined at 120 K: a three‐dimensional framework built from N—H⋯O, N—H⋯(O) 2 , N—H⋯π(arene) and C—H⋯O hydrogen bonds
Author(s) -
Wardell James L.,
Low John N.,
Glidewell Christopher
Publication year - 2006
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s0108270106013114
Subject(s) - intramolecular force , hydrogen bond , molecule , chemistry , crystallography , stereochemistry , organic chemistry
In the title compound, C 6 H 6 N 4 O 4 , the bond distances indicate significant bond fixation, consistent with charge‐separated polar forms. The molecules are almost planar and there is an intramolecular N—H⋯O hydrogen bond. The molecules are linked into a complex three‐dimensional framework structure by a combination of N—H⋯O, N—H⋯(O) 2 , N—H⋯π(arene) and C—H⋯O hydrogen bonds.