Open Access{Tris[4‐(1 H ‐pyrazol‐3‐yl)‐3‐azabut‐3‐enyl]amine}iron(II) diperchlorate monohydrate
Author(s) -
Hardie Michaele J.,
Kilner Colin A.,
Halcrow Malcolm A.
Publication year - 2004
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s010827010400407x
Subject(s) - amine gas treating , tris , hydrogen bond , trigonal crystal system , chemistry , crystallography , medicinal chemistry , stereochemistry , molecule , crystal structure , organic chemistry , biochemistry
In the title complex, [Fe(C 18 H 24 N 10 )](ClO 4 ) 2 ·H 2 O, the complex cation adopts a capped trigonal antiprismatic stereochemistry, with a long Fe–amine interaction [2.7468 (16) Å]. The Fe centre in the asymmetric unit is fully high‐spin at 100 K. Hydrogen bonding assembles dimeric units, which are then linked by further hydrogen bonding into chains running parallel to the crystallographic a axis.