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Efficient palladium catalyst systems based on the combination of bench stable biaryl phosphacycles and Pd(OAc) 2  are described for Suzuki-Miyaura cross-coupling reactions of aryl bromides and chlorides. Notably, the electronically and sterically diametric biaryl phosphacycles allowed facile coupling of sterically hindered and heterocyclic substrates.

phosphorus, sulfur, and silicon and the related elements

Designing biaryl phosphacyclic ligands: their characterization and evaluation in palladium-catalyzed Suzuki-Miyaura reactions of aryl bromides and chlorides