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In this work, BiPO 4  (BPO)-based photocatalyst was successfully synthesized by a conventional hydrothermal strategy using bismuth nitrate pentahydrate (Bi(NO 3 ) 3 ·5H 2 O) and 1-ethyl-3-methylimidazolium dihydro phosphate ([EMIm]H 2 PO 4 ). [EMIm]H 2 PO 4  can serve as a phosphorus source and surfactant. Photocatalytic activities of the photocatalysts prepared were evaluated by the destruction of rhodamine B (RhB) and tetracycline (TC) under UV light irradiation, respectively. The results reveal that the sample (IL-BPO) synthesized with the assistance of ionic liquid exhibits enhanced photocatalytic activity in comparison with the reference BiPO 4 . The significantly improved photocatalytic activity of IL-BPO can be mainly attributed to the boosted separation of photoinduced electron-hole pairs (e − /h + ) and richer oxygen vacancies (OVs).

Ionic liquids assisted preparation of BiPO 4 photocatalyst with enhanced photocatalytic activity for tetracycline and rhodamine B removal