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Eucalyptol or 1,8-cineole, a bio-based monoterpene, whose potential has been explored as a viable alternative reaction media for the development of several heterocyclic systems. As an eco-benign solvent eucalyptol has been found to be a promising, bio-competent, green media in our protocols without allowing the involvement of any transition metal catalyst at suitable temperature. In our present work, we carried out the synthesis of 2,3-dihydroquinazolin-4(1 H )-one and isoxazolone derivatives from several aldehydes by using this unexplored but effective eco-benign solvent. The use of this recyclable solvent helped us to avoid the use of hazardous, toxic, and harsh reaction conditions toward the synthesis of different desired heterocyclic systems.

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Eucalyptol: An efficient, unexplored, green media for transition metal free synthesis of 2,3-dihydroquinazolin-4(1 H )-one derivatives and isoxazolone derivatives