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Glyphosate adsorption pattern is important for determining its environmental fate. Oxisol soil systems adsorb maximum glyphosate in the presence of biochar, however, the mechanism was not known. This article provides information concerning the role of surface charge in the case of Oxisol soil systems. Potentiometric titrations were done to calculate the surface charge in the case of Oxisol soil systems. Maximum adsorption of glyphosate in the Oxisol soil systems in the presence of biochar was due to an increase in net positive surface charge. This finding is of great importance to understanding the mechanism of herbicide soil interactions.

Surface Charge Governs the Adsorption Behaviour of Glyphosate in the Australian Oxisol Soil System