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In this investigation 4-(benzo[d]thiazol-2-yl)benzenamine was reacted with aryl isothiocyanates to give 1-(4-(benzo[ d ]thiazol-2-yl)phenyl)-3-aryl thioureas 2 , which were cyclized with acid to afford 3-(4-(benzo[ d ]thiazol-2-yl)phenyl)-5-aryl-1,3,5-oxadiazinane-4-thiones 3 . On the other hand, 1-(4-(benzo[ d ]thiazol-2-yl)phenyl)-5-methyl-3-aryl-1,3,5-triazinane-2-thiones 4 were obtained when compounds 2 were treated with amines.

synopen

Synthesis of 3-(4-(Benzo[d]thiazol-2-yl)phenyl)-5-aryl-1,3,5-oxadiazinane-4-thiones and 1-(4-(Benzo[d]thiazol-2-yl)phenyl)-5-methyl-3-aryl-1,3,5-triazinane-2-thiones