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37 T . S H I B A T A, * M . FU J I M O T O , T . O T A NI ( WA S E D A U N I V E R SI T Y, S H I N J UK U , J A P A N SC I E N C E A N D TE C H N O L O G Y A G E N C Y, K A W AG U C H I , A ND TO K Y O U NI V E R S I T Y O F S C I E N C E , S H I N J UK U , J A PA N) Synthesis of Macrocyclic Heteroarylenes by Consecutive Interand Intramolecular Cycloadditions of ThiophenyleneTethered Triynes Tetrahedron 2014, 70, 8453–8461.

Not-So-Triyne Route to Heteroarylene and Arylene Macrocycles