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Disubstituted hydroxylamines were synthesized and used to form aluminum-amide complexes. These reagents masked carbonyl groups in situ from nucleophilic addition. The stability and utility of the aluminum-aminals are presented in the context of selectively controlling nucleophilic addition on substrates with multiple carbonyl groups.

Effect of Substituents and Stability of Transient Aluminum–Aminals­ in the Presence of Nucleophiles

Effect of Substituents and Stability of Transient Aluminum–Aminals in the Presence of Nucleophiles