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A range of useful disubstituted benzyl alcohol building blocks have been synthesised in multigram quantities in a lithium–bromide exchange to give aldehyde, carboxylic acid and pinacol ­boranes in high yields.

Synthesis of Benzyl Alcohol Building Blocks Bearing an Aldehyde, Pinacol Borane or Carboxylic Acid Motif via Lithium–Bromide Exchange