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Hydroxylamine (NH$_{2}$OH) and methylamine (CH$_{3}$NH$_{2}$) have both beensuggested as precursors to the formation of amino acids and are therefore ofinterest to prebiotic chemistry. Their presence in interstellar space andformation mechanisms, however, are not well established. We aim to detect bothamines and their potential precursor molecules NO, N$_{2}$O and CH$_{2}$NHtowards the low-mass protostellar binary IRAS 16293--2422, in order toinvestigate their presence and constrain their interstellar formationmechanisms around a young Sun-like protostar. ALMA observations from theunbiased, high angular resolution and sensitivity Protostellar InterferometricLine Survey (PILS) are used. Spectral transitions of the molecules underinvestigation are searched for with the CASSIS line analysis software. CH$_2$NHand N$_{2}$O are detected for the first time towards a low-mass source, thelatter molecule through confirmation with the single-dish TIMASSS survey. NO isalso detected. CH$_{3}$NH$_{2}$ and NH$_{2}$OH are not detected and stringentupper limit column densities are determined. The non-detection ofCH$_{3}$NH$_{2}$ and NH$_{2}$OH limits the importance of formation routes toamino acids involving these species. The detection of CH$_{2}$NH makes aminoacid formation routes starting from this molecule plausible. The low abundancesof CH$_2$NH and CH$_{3}$NH$_{2}$ compared to Sgr B2 indicate that differentphysical conditions influence their formation in low- and high-mass sources.

The ALMA-PILS survey: Stringent limits on small amines and nitrogen-oxides towards IRAS 16293-2422B