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The unsaturated 1,4-P/B-FLPs reduced nitrobenzene to nitrosobenzene which was directly trapped by an allylboration reaction to give the seven-membered B-O-P compounds and . The FLP reacted analogously with trans-β-nitrostyrene. The products were characterized by X-ray diffraction.

Nitro-redox reactions at a frustrated borane/phosphane Lewis pair