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Ni 83.25 Zr 16.75  peritectic alloy was containerlessly solidified in a drop tube. When the droplet diameter exceeds a critical value ( D  crit ), Ni 7 Zr 2  phase primarily solidifies, followed by the peritectic reaction of Ni 7 Zr 2  + L → Ni 5 Zr. Once the droplet diameter is smaller than the critical value ( D  crit ), peritectic phase Ni 5 Zr directly solidifies from the undercooled melt by completely suppressing the nucleation and growth of Ni 7 Zr 2  phase, which is ascribed to high undercooling and cooling rate. Additionally, peritectic phase Ni 5 Zr grows equiaxially in the sample solidified in a DSC at a cooling rate of 0.167 K/s.

Direct formation of peritectic phase but no primary phase appearance within Ni83.25Zr16.75 peritectic alloy during free fall