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While electrodeposited antimony telluride thin films with silver contents demonstrated promising thermoelectric properties, their thermal conductivity and the silver content dependence remain unknown. Here, we report the thermal conductivities of Ag 3.9 Sb 33.6 Te 62.5  and AgSbTe 2  thin films with controlled annealing and temperature conditions and demonstrate the impact of silver content on thermal transport. After annealing at 160 °C, the room-temperature thermal conductivity of Ag 3.9 Sb 33.6 Te 62.5  and AgSbTe 2  thin films increases from 0.24 to 1.59 Wm −1  K −1  and from 0.17 to 0.56 Wm −1  K −1 , respectively. Using phonon transport models and X-ray diffraction measurements, we attribute the thermal conductivity increases to the crystal growth and explain the thermal conductivity variations with the degree of crystallization. Unlike electrical properties reported in previous studies, the presence of silver contents has little impact on the thermal conductivity of Ag 3.9 Sb 33.6 Te 62.5  and leads to a strong reduction in the thermal conductivity of AgSbTe 2  thin films. By performing transient thermal conductivity measurements at 94 °C, we find the crystallization activation energy of Ag 3.9 Sb 33.6 Te 62.5  and AgSbTe 2  films as 1.14 eV and 1.16 eV, respectively. Their differences reveal the role of silver in inhibiting the nucleation and growth of Sb 2 Te 3  crystals and impeding thermal transport. These findings provide guidance for optimizing doping and annealing conditions of antimony tellurides for near-room-temperature thermoelectric applications.

Silver content dependent thermal conductivity and thermoelectric properties of electrodeposited antimony telluride thin films