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A preliminary VLT-UVES spectrum of NGC 6302 (Casassus et al. 2002, MN), whichhosts one of the hottest PN nuclei known (Teff ~ 220000 K; Wright et al. 2011,MN), has been recently analysed by means of X-SSN, a spectrum synthesis codefor nebulae (Morisset and P\'equignot). Permitted recombination lines fromhighly-ionized species are detected/identified for the first time in a PN, andsome of them probably for the first time in (Astro)Physics. The need for ahomogeneous, high signal-to-noise UVES spectrum for NGC 6302 is advocated.

NGC 6302: high-ionization permitted lines. Applying X-SSN synthesis to VLT-UVES spectra