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HighlightsSynthesis protocols, design engineering, theoretical calculations, and energy applications for metal–organic frameworks (MOFs)-derived electrocatalysts are systematically analyzed.    Synthesizing methods of MOF-derived catalysts and their oxygen reduction reaction, oxygen evolution reaction, and hydrogen evolution reaction electrocatalysis are discussed.    The current status, ongoing challenges, and potential future outlooks of MOFs-derived electrocatalysts are highlighted.

Design Engineering, Synthesis Protocols, and Energy Applications of MOF-Derived Electrocatalysts