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HighlightsThe traditional and novel etching methods are summarized and compared, especially fluorine-free method. The methods for accelerating exfoliation of Ti 3 C 2 T  x   are classified.    The energy storage mechanisms of Ti 3 C 2 T  x   in different electrolytes are compared. Based on energy storage mechanisms, the influencing factors of morphology and surface functional groups are discussed.    In response to the problems of the Ti 3 C 2 T  x  , strategies for improving capacitance from structure modulation to composite structure construction are summarized and compared.

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Enhancing Capacitance Performance of Ti3C2Tx MXene as Electrode Materials of Supercapacitor: From Controlled Preparation to Composite Structure Construction