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HighlightsTitania-coated Au nanobipyramids (NBP@TiO 2 ) with a high photothermal conversion efficiency in the NIR-II window are synthesized.    The TiO 2  shell is capable for the loading of the anticancer drug combretastatin A-4 phosphate (CA4P).    The CA4P-loaded NBP@TiO 2  nanostructures subjected with photothermal therapy induce synergistic anticancer and antiangiogenesis effects under 1064-nm laser irradiation at a power density lower than the skin tolerance threshold value.Electronic supplementary material  The online version of this article (10.1007/s40820-019-0327-4) contains supplementary material, which is available to authorized users.

Antiangiogenesis-Combined Photothermal Therapy in the Second Near-Infrared Window at Laser Powers Below the Skin Tolerance Threshold