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HighlightsA viable bio-derived material engineering strategy is developed based on the use of skin collagen fibers for the crafting of metal-nitride–carbon nanofiber composites.    N-doped carbon nanofiber bundles embedded with Fe 2 N nanoparticles are fabricated using a structural replication process.    The composite with a hierarchically ordered, compact, and multicore–shell heterostructure exhibits increased lithium- and potassium-ion storage performances.Electronic supplementary material  The online version of this article (10.1007/s40820-019-0290-0) contains supplementary material, which is available to authorized users.

nano-micro letters

Bio-Derived Hierarchical Multicore–Shell Fe2N-Nanoparticle-Impregnated N-Doped Carbon Nanofiber Bundles: A Host Material for Lithium-/Potassium-Ion Storage