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HighlightsPourbaix diagram of Mn–Zn–H 2 O system was used to analyze the charge–discharge processes of Zn/MnO 2  batteries.    Electrochemical reactions with the participation of various ions inside Zn/MnO 2  batteries were revealed.    A detailed explanation of phase evolution inside Zn/MnO 2  batteries was provided.Electronic supplementary material  The online version of this article (10.1007/s40820-019-0278-9) contains supplementary material, which is available to authorized users.

Novel Insights into Energy Storage Mechanism of Aqueous Rechargeable Zn/MnO2 Batteries with Participation of Mn2+