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HighlightsDoping and porosity generation were completed simultaneously.    Metal–heteroatom-doped carbon nanofibers are flexible, porous, and well dispersed.    Results include excellent oxygen reduction reaction and enhanced Zn–air battery performance.Electronic supplementary material  The online version of this article (doi:10.1007/s40820-019-0238-4) contains supplementary material, which is available to authorized users.

Flexible, Porous, and Metal–Heteroatom-Doped Carbon Nanofibers as Efficient ORR Electrocatalysts for Zn–Air Battery