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This paper presents results of an experimental study to characterize the law of mineral change of fallen rock in coal mine groundwater reservoir ant its influence on water quality. The minerals of the underground reservoir of Daliuta Coal Mine is taken as the research object. Simulation experiments were designed and conducted to simulate water–rock action in the laboratory. The mineral composition was analyzed by X-ray diffractometer (XRD), the surface morphology of the mineral was analyzed by scanning electron microscope (SEM), and the specific surface area, total pore volume and average pore diameter of the mineral were measured by fast specific surface/pore analyzer (BET). The experimental results show that the sandstone and mudstone in the groundwater reservoir of Daliuta Coal Mine account for 70% and 30%, respectively. The pore diameter is 15.62–17.55 nm, and pore volume is 0.035 cc/g. Its pore structure is a key factor in the occurrence of water–rock interaction. According to the water–rock simulation experiment, the quartz content before the water–rock action is about 34.28%, the albite is about 21.84%, the feldspar is about 17.48%, and the kaolinite is about 8.00%. After the water–rock action, they are 36.14%, 17.78%, 11.62%, and 16.75%, respectively. The content of albite and orthoclase is reduced while the content of kaolinite is increased, that is, the Na +  content becomes higher, and the Ca 2+  and Mg 2+  contents become lower. This research builds a good theoretical foundation for revealing the role of water and rock in underground coal reservoirs.

Understanding of mineral change mechanisms in coal mine groundwater reservoir and their influences on effluent water quality: a experimental study