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Five previously undescribed guanacastane diterpenoids, namely psathyrellins A–E ( 1 – 5 ), were obtained from cultures of the mushroom  Psathyrella candolleana . Their structures with absolute configurations were elucidated by extensive spectroscopic methods. Compounds  1 – 3  showed antibacterial activity against four strains with MIC values in a range of 16–128 μg/mL.    Graphic AbstractSupplementary Information  The online version contains supplementary material available at 10.1007/s13659-021-00316-x.

Psathyrellins A–E, Antibacterial Guanacastane Diterpenoids from Mushroom Psathyrella candolleana