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The resonant X-ray emission spectroscopy around Ti k-edge was applied to probe local electronic structure of TiO2 rutile and anatase. By measuring 1s→3d excitation and 3p→1s decay channel, differences between localized and delocalized orbitals were determined. The 3d pre-edge structures were compared with ab initio multiple scattering simulations.

Determination of conduction and valence band electronic structure of anatase and rutile TiO 2