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Functional nano-templates enable self-assembly of otherwise impossiblearrangements of molecules. A particular class of such templates is that of sp2hybridized single layers of hexagonal boron nitride or carbon (graphene) onmetal supports. If the substrate and the single layer have a lattice mismatch,superstructures are formed. On substrates like rhodium or ruthenium thesesuperstructures have unit cells with ~3 nm lattice constant. They arecorrugated and contain sub-units, which behave like traps for molecules orquantum dots, which are small enough to become operational at room temperature.For graphene on Rh(111) we emphasize a new structural element of small extrahills within the corrugation landscape. For the case of molecules like water itis shown that new phases assemble on such templates, and that they can be usedas "nano-laboratories" where many individual processes are studied in parallel.Furthermore, it is shown that the h-BN/Rh(111) nanomesh displays a strongscanning tunneling microscopy induced luminescence contrast within the 3 nmunit cell which is a way to address trapped molecules and/or quantum dots.

Corrugated single layer templates for molecules: From h-BN Nanomesh to Graphene based Quantum dot arrays