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In this work, the desulfurization ability of alkyl-piperidinium-based and phosphonium-based ionic liquids (ILs) for (thiophene or benzothiophene + heptane) mixtures are studied. With this aim, ternary liquid-liquid phase equilibrium data (LLE) have been obtained for mixtures of {IL (1) + thiophene, or benzothiophene (2) + heptane (3)} at T  = 308.15 K and p  = 101.33 kPa. For this study 1-pentyl-1-methylpiperidinium bis{(trifluoromethyl)sulfonyl}imide, [C 1 C 5 PIP][NTf 2 ], and tributylethylphosphonium diethylphosphate, [P 2,4,4,4 ][DEP], were used. The suitability of these ILs as solvents for extractive desulfurization has been evaluated in terms of the solute distribution ratio and selectivity. Immiscibility was observed in the binary liquid systems of (thiophene, or benzothiophene + heptane) with both ILs. One of the studied ILs, [C 1 C 5 PIP][NTf 2 ], shows high distribution ratios and high selectivities for extraction of sulfur compounds. The data obtained have been correlated with the non-random two liquid NRTL model. The experimental tie-lines and the phase compositions in mole fractions in the ternary systems were calculated with an average root mean square deviation of 0.0052.

Ternary Liquid–Liquid Equilibria for Mixtures of {Ionic Liquid + Thiophene or Benzothiophene + Heptane} at T = 308.15 K