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The electronic structure of the three main vanadium oxides—V 2 O 3 , VO 2  and V 2 O 5 —is reviewed. The optical properties of vanadium pentoxide thin films were determined. It was found that a direct allowed transition is the most probable one in the studied vanadium pentoxide thin films.

Optical properties and electronic structure of V2O5, V2O3 and VO2