English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Two types of non-integer electron-exchange numbers from uniform and reversible surface-redox reactions without side reactions have been distinguished. The first being the apparent number, napp, of the apparent faradaic charge corresponding to cyclovoltammetric peak areas above the interpolated baseline, and the second the thermodynamically defined surface-redox valency, n’, of Nernstian slopes of cyclovoltammetric peak potentials depending on different solution pH. An analytical expression has been derived for napp based on a simplified capacitive equivalent circuit and for n’ using the potential-dependent free adsorption energies of the reactants involved. It should be pointed out that the different experimental values of napp and n’ refer to the same integer number of electrons per molecule oxidized or reduced.

The non-integer cyclovoltammetric electron-exchange numbers of reversible redox reactions of adsorbates